Water quality monitoring system - Darwin Harbour, Northern Territory

Brief description

Darwin Harbour is a tropical estuarine system with a distinct wet and dry season and is one of Australia's largest deep water harbours (Russell and Hewitt 2000). The annual rainfall of Darwin averages 1714 mm, with 64% of this falling between January and March. The harbour is macro-tidal, with a maximum tidal range of 7.8 m and strong currents of up to 2 m/s that transport sediment within the harbour. Nine sites were sampled throughout the harbour on a quarterly basis at the neap tides between December 2002 and December 2004. Sites ranged in depth from 5 m (river sites) to 30 m (outer harbour sites). Highly seasonal rainfall in this region greatly affects the water quality throughout Darwin Harbour, with the results from this study showing that seasonal aspects, rather than spatial or tidal, are more important in causing significant differences in water quality. However, while nutrient, suspended solid and chlorophyll a concentrations differed between locations within the harbour, rainfall appears to have the greatest impact on these parameters. Darwin Harbour is a well mixed, though not a well-flushed system, with a huge tidal range that causes large volumes of water to move into and out of the harbour. This in turn leads to considerable differences in water mixing between different areas within the harbour and so one would expect that the concentrations of nutrients, chlorophyll a and suspended solids would be greatly influenced by this. Interestingly, our observations did not detect significant variations during the tidal studies, but did detect significant differences between wet and dry seasons. Darwin Harbour water quality, as observed during this study, was not significantly different to that observed by Padovan (1997) 12 years prior to this study. This is despite the considerable alterations and developments in the harbour and the surrounding catchment during this period. This study was undertaken to expand the existing monitoring work in the harbour carried out by the Northern Territory Department of Natural Resources, Environment and The Arts (NRETA) and to provide additional baseline information of water quality. Parameters measured: temperature, salinity, turbidity, nutrients, chlorophyll a, particulate nitrogen, particulate phosphorus and suspended solids concentrations.

Lineage

Maintenance and Update Frequency: notPlanned

Statement: Statement: Chlorophyll a concentrations are measured fluorometically using a Turner designs 10AU fluorometer after grinding the filters in 90% acetone [Parsons, T.R., Maita,Y. and Lalli, C.M. (1984). Dissolved inorganic nutrients (ammonium, nitrite, nitrate, phosphate and silica) concentrations were determined using a segmented flow analyser (Ryle et al., 1981). Dissolved organic nitrogen and dissolved organic phosphorus concentrations were calculated as the difference between total dissolved inorganic nitrogen and phosphorus concentrations measured in filtered seawater irradiated for 6-8 hours with UV light and the previously determined dissolved inorganic nitrogen and phosphorus concentrations in unirradiated samples. Particulate nitrogen was determined by high-combustion of the dried pre-ashed glass fibre filters with an ANTEK 9000 NS analyser. Particulate phosphorus was determined by refluxing the pre-ashed glass fibre filters and their associated organic matter to dryness with acid persulfate (5%), redissolving the digest in deionised water and colorimetrically determining the phosphate content of the supernatant (Parsons et al. 1984). The concentrations of suspended solids were determined by drying the pre-weighed 0.4 um filters at 60 oC and re-weighing them.

Notes

Credit
McKinnon, A David, Dr (Principal Investigator)