grant

Polymerization Mechanism and Kinetics of 1,1-Disubstituted Monomers [ 2002-02-01 - 2005-06-30 ]

Research Grant

[Cite as https://purl.org/au-research/grants/arc/DP0208453]

Researchers: Dr Johan (Hans) Heuts (Chief Investigator) ,  Tom Davis (Chief Investigator)

Brief description Polymerization Mechanism and Kinetics of 1,1-Disubstituted Monomers. This project focuses on two exciting research areas: (I) we have found that an oxygen atom b to the double bond activates radical polymerization, making a whole new family of polymeric structures accessible, and (II) we have strong preliminary data that demonstrates a very large solvent effect on propagation and termination reactions for acrylic monomers with an a-CH2OH functionality, suggesting that significant control can be exerted over the polymerization process using additives. Additionally, we demonstrate that polymers containing repeat units with an a-CH2OH functionality can undergo reversible cyclization, enabling a whole range of novel functional materials.

Funding Amount $185,000

Funding Scheme Discovery Projects

View this grant in the ARC Data Portal

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Identifiers
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ACN 633 798 857