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Data from: Protic Ionic Liquids: Evolving Structure–Property Relationships and Expanding Applications

RMIT University, Australia
Dr Tamar Greaves (Associated with, Aggregated by)
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ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rfr_id=info%3Asid%2FANDS&rft_id=https://figshare.com/articles/Protic_Ionic_Liquids_Evolving_Structure_Property_Relationships_and_Expanding_Applications/2116936&rft.title=Data from: Protic Ionic Liquids: Evolving Structure–Property Relationships and Expanding Applications&rft.identifier=06163ad89471f0c4808f3386dd87fc62&rft.publisher=RMIT University, Australia&rft.description=Attached file provides supplementary data for linked article. Thermal phase behavior of the PILs in Table S1, and the physicochemical properties of PILs in Table S2; references 608−635 are not cited in the main text, but are referred to within the Supporting Information. The thermal and physicochemical properties of protic ionic liquids (PILs) are reported. It is highly evident that there has been an extensive range of alkylammonium, imidazolium, and heterocyclic cations paired with many organic and inorganic anions that have been employed to prepare PILs. There has been strong interest in modifying the properties of PILs through the addition of water or other molecular solvents. For many applications, the presence of some water in the PILs is not detrimental, and instead leads to enhanced solvent properties such as lower viscosity, higher conductivities, and lower melting points. It remains an issue of definition though of how to refer to these resulting protic solutions. There is also an ongoing difficulty surrounding how to describe the proton activity in the PILs, analogous to pH in aqueous systems. For a broad range of applications, it has been reported that the acidity/basicity of the PIL or PIL-solvent system is crucial for their beneficial properties. It is expected that the fundamental properties of PILs will continue to be explored, along with continued interest in many existing and new applications, such as in electrochemistry, organic and inorganic synthesis, and biological applications. In particular, there has been a significant interest in a broad- range of PILs for use as electrolytes and incorporation in polymer electrolytes for fuel cells, and other energy storage devices.&rft.creator=Dr Tamar Greaves&rft.date=2018&rft.relation=http://dx.doi.org/10.1021/acs.chemrev.5b00158&rft_rights=All rights reserved &rft_rights=CC BY-NC: Attribution-Noncommercial 3.0 AU http://creativecommons.org/licenses/by-nc/3.0/au&rft_subject=Electrolytes&rft_subject=Protic ionic liquids &rft_subject=Solvent properties&rft_subject=Structure property relationships&rft_subject=Fuel cells&rft_subject=Fuel storage&rft_subject=Polyelectrolytes&rft_subject=Solvents&rft_subject=Biological applications&rft_subject=Fundamental properties&rft_subject=Inorganic synthesis&rft_subject=Physicochemical property&rft_subject=Physical Chemistry not elsewhere classified&rft_subject=CHEMICAL SCIENCES&rft_subject=PHYSICAL CHEMISTRY (INCL. STRUCTURAL)&rft.type=dataset&rft.language=English Access the data
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Attached file provides supplementary data for linked article. Thermal phase behavior of the PILs in Table S1, and the physicochemical properties of PILs in Table S2; references 608−635 are not cited in the main text, but are referred to within the Supporting Information. The thermal and physicochemical properties of protic ionic liquids (PILs) are reported. It is highly evident that there has been an extensive range of alkylammonium, imidazolium, and heterocyclic cations paired with many organic and inorganic anions that have been employed to prepare PILs. There has been strong interest in modifying the properties of PILs through the addition of water or other molecular solvents. For many applications, the presence of some water in the PILs is not detrimental, and instead leads to enhanced solvent properties such as lower viscosity, higher conductivities, and lower melting points. It remains an issue of definition though of how to refer to these resulting protic solutions. There is also an ongoing difficulty surrounding how to describe the proton activity in the PILs, analogous to pH in aqueous systems. For a broad range of applications, it has been reported that the acidity/basicity of the PIL or PIL-solvent system is crucial for their beneficial properties. It is expected that the fundamental properties of PILs will continue to be explored, along with continued interest in many existing and new applications, such as in electrochemistry, organic and inorganic synthesis, and biological applications. In particular, there has been a significant interest in a broad- range of PILs for use as electrolytes and incorporation in polymer electrolytes for fuel cells, and other energy storage devices.

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Biological applications | Chemical Sciences | Electrolytes | Fuel cells | Fuel storage | Fundamental properties | Inorganic synthesis | Physical Chemistry (Incl. Structural) | Physical Chemistry Not Elsewhere Classified | Physicochemical property | Polyelectrolytes | Protic ionic liquids | Solvent properties | Solvents | Structure property relationships |

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  • Local : 06163ad89471f0c4808f3386dd87fc62
ACN 633 798 857