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Data from: Phosphoric acid loaded azo (-N=N-) based covalent organic framework for proton conduction

RMIT University, Australia
Dr Ravichandar Babarao (Associated with, Aggregated by)
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ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rfr_id=info%3Asid%2FANDS&rft_id=https://figshare.com/articles/Phosphoric_Acid_Loaded_Azo_N_N_Based_Covalent_Organic_Framework_for_Proton_Conduction/2299642&rft.title=Data from: Phosphoric acid loaded azo (-N=N-) based covalent organic framework for proton conduction&rft.identifier=4cacf01b2633db2316a17c4e7a8f0e53&rft.publisher=RMIT University, Australia&rft.description=Attached file provides supplementary data for linked article. Two new chemically stable functional crystalline covalent organic frameworkds (COFs) (Tp-Azo and Tp-Stb) were synthesized using the Schiff base reaction between triformylphloroglucinol (Tp) and 4,4-azodianiline (Azo) or 4,4-diaminostilbene (Stb), respectively. Both COFs show the expected keto-enamine form, and high stability toward boiling water, strong acidic, and basic media. H3PO4 doping in Tp-Azo leads to immobilization of the acid within the porous framework, which facilitates proton conduction in both the hydrous (O= 9.9 × 10-4 S cm -1) and anhydrous state (O= 6.7 × 10-5 S cm -1). This report constitutes the first emergence of COFs as proton conducting materials.&rft.creator=Dr Ravichandar Babarao&rft.date=2018&rft.relation=http://dx.doi.org/10.1021/ja502212v&rft_rights=Further information about rights and usage of ACS publications and supplementary data can be found here: http://pubs.acs.org/page/copyright/permissions.html.&rft_rights=CC BY-NC: Attribution-Noncommercial 3.0 AU http://creativecommons.org/licenses/by-nc/3.0/au&rft_subject=Coordination polymers&rft_subject=Crystalline&rft_subject=Hydrogen&rft_subject=Storage&rft_subject=Membranes&rft_subject=Condensed Matter Modelling and Density Functional Theory&rft_subject=PHYSICAL SCIENCES&rft_subject=CONDENSED MATTER PHYSICS&rft.type=dataset&rft.language=English Access the data
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Attached file provides supplementary data for linked article. Two new chemically stable functional crystalline covalent organic frameworkds (COFs) (Tp-Azo and Tp-Stb) were synthesized using the Schiff base reaction between triformylphloroglucinol (Tp) and 4,4-azodianiline (Azo) or 4,4-diaminostilbene (Stb), respectively. Both COFs show the expected keto-enamine form, and high stability toward boiling water, strong acidic, and basic media. H3PO4 doping in Tp-Azo leads to immobilization of the acid within the porous framework, which facilitates proton conduction in both the hydrous (O= 9.9 × 10-4 S cm -1) and anhydrous state (O= 6.7 × 10-5 S cm -1). This report constitutes the first emergence of COFs as proton conducting materials.

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Condensed Matter Physics | Condensed Matter Modelling and Density Functional Theory | Coordination polymers | Crystalline | Hydrogen | Membranes | Physical Sciences | Storage |

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  • Local : 4cacf01b2633db2316a17c4e7a8f0e53
ACN 633 798 857