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Data from: Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to cis-[(dppe)M(κC‑2‑C6F4PPh2)2] (M = Ni, Pd, and Pt)

RMIT University, Australia
Suresh Kumar Bhargava (Aggregated by)
Viewed: [[ro.stat.viewed]] Cited: [[ro.stat.cited]] Accessed: [[ro.stat.accessed]]
ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Adc&rfr_id=info%3Asid%2FANDS&rft_id=https://figshare.com/articles/Formation_of_Heterobimetallic_Complexes_by_Addition_of_d_sup_10_sup_-Metal_Ions_to_i_cis_i_-_dppe_M_i_C_i_2_C_sub_6_sub_F_sub_4_sub_PPh_sub_2_sub_sub_2_sub_M_Ni_Pd_and_Pt_/5350948&rft.title=Data from: Formation of Heterobimetallic Complexes by Addition of d10-Metal Ions to cis-[(dppe)M(κC‑2‑C6F4PPh2)2] (M = Ni, Pd, and Pt)&rft.identifier=5d0b34420dcad3e7abbe0b20df8b3e79&rft.publisher=RMIT University, Australia&rft.description=Attached file provides supplementary data for linked article. The reactivity of [(dFFe)M(kappa C-2-C6F4PPh2)(2)] (M = Ni (1Ni), Pd (1Pd), and Pt (lPt); dppe = 1,2-bis(diphenylphosphino)ethane)) toward monovalent coinage metal ions (M' = Cu, Ag, and Au) has been investigated. Two main isomers adppe)M(kappa C-2-C6F4PPh2)(mu-2-C6F4PPh2)M'Cl] (2PdAg, 2PdAu, 2PtCu, 2PtAg, and 2PtAu) and [(dppe)M(mu-2-C6F4PPh2)(2)M'Cl] (3PdCu, 3PdAg, and 3PtCu) could be detected. Quantum chemical calculations underpin the enhanced thermodynamic stability of [(dppe)M(kappa C-2-C6F4PPh2)(mu(2)-C6F4PPh2)M'Cl] for combinations of the heavier metals. NBO calculations reveal attractive Pt Cu and Pt-Ag interactions in complexes 2PtCu and 2PtAg, respectively. From the reaction of [(dppe)M(kappa C-2-C6F4PPh2)(2)] with an excess of [AuCI(tht)], a series of trinuclear complexes [(dPpe)M(mu-2-C6F4PPh2)(2).(AuCI)(2)] (4NiAu(2), 4PdAu(2), and 4PtAu(2)) was prepared. Reaction of [(dppe)M(kappa C-2-C6F4PPh2)(mu-2C(6)F(4)PPh(2))M'Cl] with T1PF(6) leads to the formation of cationic derivatives [(dppe)M(mu-2-C6F4PPh2)(2)M']PF6 with P-M'-P (6PtAu) or P-M'-C (7PdAu, 7PtAu) bonding situations around the coinage metal.&rft.creator=Suresh Kumar Bhargava&rft.date=2018&rft.relation=https://dx.doi.org/10.1021/acs.organomet.7b00145&rft_rights=Further information about rights and usage of ACS publications and supplementary data can be found here: http://pubs.acs.org/page/copyright/permissions.html&rft_rights=CC BY-NC: Attribution-Noncommercial 3.0 AU http://creativecommons.org/licenses/by-nc/3.0/au&rft_subject=D(8)-D(10) Complexes&rft_subject=Carbanion 2-C6F4PPH2&rft_subject=Dinuclear complexes&rft_subject=Crystal structures &rft_subject=Ligands&rft_subject=Palladium (II)&rft_subject=Borane&rft_subject=Gold&rft_subject=Copper&rft_subject=Chemical Sciences not elsewhere classified&rft_subject=CHEMICAL SCIENCES&rft_subject=OTHER CHEMICAL SCIENCES&rft.type=dataset&rft.language=English Access the data
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Attached file provides supplementary data for linked article. The reactivity of [(dFFe)M(kappa C-2-C6F4PPh2)(2)] (M = Ni (1Ni), Pd (1Pd), and Pt (lPt); dppe = 1,2-bis(diphenylphosphino)ethane)) toward monovalent coinage metal ions (M' = Cu, Ag, and Au) has been investigated. Two main isomers adppe)M(kappa C-2-C6F4PPh2)(mu-2-C6F4PPh2)M'Cl] (2PdAg, 2PdAu, 2PtCu, 2PtAg, and 2PtAu) and [(dppe)M(mu-2-C6F4PPh2)(2)M'Cl] (3PdCu, 3PdAg, and 3PtCu) could be detected. Quantum chemical calculations underpin the enhanced thermodynamic stability of [(dppe)M(kappa C-2-C6F4PPh2)(mu(2)-C6F4PPh2)M'Cl] for combinations of the heavier metals. NBO calculations reveal attractive Pt Cu and Pt-Ag interactions in complexes 2PtCu and 2PtAg, respectively. From the reaction of [(dppe)M(kappa C-2-C6F4PPh2)(2)] with an excess of [AuCI(tht)], a series of trinuclear complexes [(dPpe)M(mu-2-C6F4PPh2)(2).(AuCI)(2)] (4NiAu(2), 4PdAu(2), and 4PtAu(2)) was prepared. Reaction of [(dppe)M(kappa C-2-C6F4PPh2)(mu-2C(6)F(4)PPh(2))M'Cl] with T1PF(6) leads to the formation of cationic derivatives [(dppe)M(mu-2-C6F4PPh2)(2)M']PF6 with P-M'-P (6PtAu) or P-M'-C (7PdAu, 7PtAu) bonding situations around the coinage metal.

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Borane | Chemical Sciences | Carbanion 2-C6F4PPH2 | Chemical Sciences Not Elsewhere Classified | Copper | Crystal structures | D(8)-D(10) Complexes | Dinuclear complexes | Gold | Ligands | Other Chemical Sciences | Palladium (II) |

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